Spectrochemical Studies on Iridium Complexes. I
نویسندگان
چکیده
منابع مشابه
Synthesis of new heteroscorpionate iridium(I) and iridium(III) complexes.
The reactivity of different heteroscorpionate ligands based on bis(pyrazol-1-yl)methane, with different iridium-(i) and -(iii) precursors is reported. The reaction of the heteroscorpionate lithium salts "Li(bdmpza)", [bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate], "Li(bdmpzdta)" [bdmpzdta = bis(3,5-dimethylpyrazol-1-yl)dithioacetate] and "Li(S)-mbpam" [(S)-mbpam = (S)-(-)-N-α-methylbenzyl-2,2-...
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The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1951
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.72.787